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Highly selective metal recovery from spent lithium-ion batteries through stoichiometric hydrogen ion

Weiguang Lv, Xiaohong Zheng, Li Li, Hongbin Cao, Yi Zhang, Renjie Chen, Hancheng Ou, Fei Kang, Zhi Sun

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1243-1256 doi: 10.1007/s11705-020-2029-3

Abstract: Spent lithium-ion battery recycling has attracted significant attention because of its importance inIn this research, we demonstrate a method to selectively recover lithium before the leaching of other

Keywords： recycling     spent LIBs     selective recovery     hydrothermal treatment    

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A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries Review

Xiaohong Zheng, Zewen Zhu, Xiao Lin, Yi Zhang, Yi He, Hongbin Cao, Zhi Sun

Engineering 2018, Volume 4, Issue 3,   Pages 361-370 doi: 10.1016/j.eng.2018.05.018

Abstract:

The rapid growth of lithium ion batteries (LIBs) for portable electronic devices and electric vehicleshas resulted in an increased number of spent LIBs.Spent LIBs contain not only dangerous heavy metals but also toxic chemicals that pose a serious threatTherefore, a great deal of attention has been paid to the development of an efficient process to recycle spentIn this paper, we review the state-of-the-art processes for metal recycling from spent LIBs, introduce

Keywords： Spent lithium ion batteries     Valuable metals     Pretreatment     Metal extraction     Product preparation     Recycling    

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Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 5,   Pages 792-796 doi: 10.1007/s11783-014-0705-6

Abstract: The amount of spent rechargeable lithium batteries (RLBs) is growing rapidly owing to wide applicationof these batteries in portable electronic devices and electric vehicles, which obliges that spent RLBsIdentification of spent RLBs can supply fundamental information for spent RLBs recycling.study aimed to determine the differences of physical components and chemical compositions among various spent

Keywords： rechargeable lithium batteries     e-waste     physical components     difference analysis     recycling    

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Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 5, doi: 10.1007/s11783-017-0993-8

Abstract: With extensive use of lithium ion batteries (LIBs), amounts of LIBs were discarded, giving rise to growthIn view of wide usage of natural graphite and the high content (12%–21%) of anode graphite in spent LIBs, recycling anode graphite from spent LIBs cannot only alleviate the shortage of natural graphite, but

Keywords： Spent LIBs     Graphite     Graphite oxide     Grapheme    

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A review on the development of electrolytes for lithium-based batteries for low temperature applications

Frontiers in Energy 2023, Volume 17, Issue 1,   Pages 43-71 doi: 10.1007/s11708-022-0853-5

Abstract: The aerospace industry relies heavily on lithium-ion batteries in instrumentation such as satellitesdemands for greater energy storage rise, new materials also need to be adopted involving next generation lithium-ionWith these objectives in mind, tailoring of the electrolyte with higher-capacity materials such as lithiumreview paper highlights the progression of electrolyte research for low temperature performance of lithium-ionbatteries over the previous several decades.

Keywords： electrolyte     lithium-ion     low temperature     aerospace     solid-electrolyte interface    

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Two-phase early prediction method for remaining useful life of lithium-ion batteries based on a neural

Frontiers in Energy doi: 10.1007/s11708-023-0906-4

Abstract: Lithium-ion batteries (LIBs) are widely used in transportation, energy storage, and other fields.The prediction of the remaining useful life (RUL) of lithium batteries not only provides a referenceBy testing four batteries under different working conditions, the RMSE of all capacity estimation is

Keywords： lithium-ion batteries     RUL prediction     double exponential model     neural network     Gaussian process regression    

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Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries

Jingning SHAN, Xiaofang YANG, Chao YAN, Yiguang JU, Lin CHEN, Fang ZHAO

Frontiers in Energy 2019, Volume 13, Issue 4,   Pages 626-635 doi: 10.1007/s11708-019-0650-y

Abstract: Single wall carbon nanotube (SWCNT) additives were formulated into µm-Si-graphite composite electrodes and tested in both half cells and full cells with high nickel cathodes. The critical role of small amount of SWCNT addition (0.2 wt%) was found for significantly improving delithiation capacity, first cycle coulombic efficiency (FCE), and capacity retention. Particularly, Si (10 wt%)-graphite electrode exhibits 560 mAh/g delithiation capacity and 92% FCE at 0.2 C during the first charge-discharge cycle, and 91% capacity retention after 50 cycles (0.5 C) in a half cell. Scanning electron microscope (SEM) was used to illustrate the electrode morphology, compositions and promoting function of the SWCNT additives. In addition, full cells assembled with high nickel-NCM811 cathodes and µm-Si-graphite composite anodes were evaluated for the consistence between half and full cell performance, and the consideration for potential commercial application. Finally, criteria to assess Si-containing anodes are proposed and discussed from an industrial perspective.

Keywords： lithium-ion battery     Si anode     Si-graphite composite     single wall carbon nanotube (SWCNT)     NCM811    

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Fabrication of layered structure VS anchor in 3D graphene aerogels as a new cathode material for lithiumion batteries

Frontiers in Energy 2019, Volume 13, Issue 3,   Pages 597-602 doi: doi:10.1007/s11708-018-0576-9

Abstract: more and more attention for its high theoretical capacity (449 mAh/g with 3e− transfer) in lithiumion batteries (LIBs).

Keywords： VS4     graphene aerogels     cathode     lithium storage    

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Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries Review

Xue-Qiang Zhang, Chen-Zi Zhao, Jia-Qi Huang, Qiang Zhang

Engineering 2018, Volume 4, Issue 6,   Pages 831-847 doi: 10.1016/j.eng.2018.10.008

Abstract:

Rechargeable lithium-ion batteries (LIBs) afford a profound impact on our modern daily life.Next-generation lithium (Li) batteries, which employ Li metal as the anode and intercalation or conversionThis review starts by summarizing the electrolytes for next-generation Li batteries.Key challenges and recent progress in lithium-ion, lithium–sulfur, and lithium–oxygen batteriesFinally, possible directions for further development in Li batteries are presented.

Keywords： Lithium-ion batteries     Lithium–sulfur batteries     Lithium–oxygen batteries     Lithium metal     Solid-state batteries    

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Lithium-ion modified cellulose as a water-soluble binder for Li-O battery

Frontiers in Energy 2022, Volume 16, Issue 3,   Pages 502-508 doi: 10.1007/s11708-021-0750-3

Abstract: An environment-friendly, water-soluble, and cellulose based binder (lithium carboxymethyl cellulose,Li-O2 batteries based on the CMC-Li binder present enhanced discharge specific capacitiesenhanced performance may originate from the electrochemical stability of the CMC-Li binder and the ion-conductivecan be a green substitute for poly(vinylidene fluoride) (PVDF) binder based on organic solvent in the lithiumoxygen batteries (LOBs).

Keywords： cellulose     binder     specific capacity     cyclabi- lity     lithium-oxygen batteries    

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Ion conduction path in composite solid electrolytes for lithium metal batteries: from polymer rich to

Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 706-733 doi: 10.1007/s11708-022-0833-9

Abstract: Solid-state electrolytes (SSEs) can address the safety issue of organic electrolyte in rechargeable lithiumbatteries.and brittle but more conducting ceramics can take advantage of the individual system for solid-state lithiummetal batteries (SSLMBs).understanding of recent advances and limitations of both PR and CR electrolytes, with a special focus on the ion

Keywords： composite solid electrolytes     active filler/framework     ion conduction path     interphase compatibility    

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Preparation of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its

Frontiers of Chemical Science and Engineering 2023, Volume 18, Issue 1, doi: 10.1007/s11705-023-2376-y

Abstract: Biomass-derived carbon materials for lithium-ion batteries emerge as one of the most promising anodes

Keywords： biomass-derived carbon     MnO2     lithium-ion batteries     anode material     high reversible capacity    

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A modified pulse charging method for lithium-ion batteries by considering stress evolution, charging

Yanfei ZHAO, Bo LU, Yicheng SONG, Junqian ZHANG

Frontiers of Structural and Civil Engineering 2019, Volume 13, Issue 2,   Pages 294-302 doi: 10.1007/s11709-018-0460-z

Abstract: The stress evolution, total charging time and capacity utilization of pulse charging (PC) method are investigated in this paper. It is found that compared to the conventional constant current (CC) charging method, the PC method can accelerate the charging process but will inevitably cause an increase in stress and a decrease in capacity. The charging speed for PC method can be estimated by the mean current. By introducing stress control, a modified PC method called the PCCC method, which starts with a PC operation followed by a CC operation, is proposed. The PCCC method not only can accelerate charging process but also can avoid the stress raising and capacity loss occurring in the PC method. Furthermore, the optimal pulsed current density and switch time in the PCCC method is also discussed.

Keywords： fast charging method     pulse charging     stress evolution     charging time     capacity utilization    

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coated LiNi0.5Mn1.5O4 as the high performance cathode materials for lithium-ionbatteries

Shifeng YANG, Wenfeng REN, Jian CHEN

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 374-382 doi: 10.1007/s11708-017-0494-2

Abstract: preparation of Li SiO -coated LiNi Mn O materials by sintering the SiO -coated nickel-manganese oxides with lithiumWhen used as the cathode materials for lithium-ion batteries, the Li SiO -coated LiNi Mn O samples deliver

Keywords： lithium-ion batteries     cathode material     LiNi0.5Mn1.5O4     lithium-ion conductor    

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Development of Lithium-Ion Batteries Wins Nobel Prize

Sean O’Neill

Engineering 2020, Volume 6, Issue 5,   Pages 487-488 doi: 10.1016/j.eng.2020.03.010

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Highly selective metal recovery from spent lithium-ion batteries through stoichiometric hydrogen ion

Weiguang Lv, Xiaohong Zheng, Li Li, Hongbin Cao, Yi Zhang, Renjie Chen, Hancheng Ou, Fei Kang, Zhi Sun

Journal Article

A Mini-Review on Metal Recycling from Spent Lithium Ion Batteries

Xiaohong Zheng, Zewen Zhu, Xiao Lin, Yi Zhang, Yi He, Hongbin Cao, Zhi Sun

Journal Article

Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

Journal Article

Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

Journal Article

A review on the development of electrolytes for lithium-based batteries for low temperature applications

Journal Article

Two-phase early prediction method for remaining useful life of lithium-ion batteries based on a neural

Journal Article

Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries

Jingning SHAN, Xiaofang YANG, Chao YAN, Yiguang JU, Lin CHEN, Fang ZHAO

Journal Article

Fabrication of layered structure VS anchor in 3D graphene aerogels as a new cathode material for lithiumion batteries

Journal Article

Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries

Xue-Qiang Zhang, Chen-Zi Zhao, Jia-Qi Huang, Qiang Zhang

Journal Article

Lithium-ion modified cellulose as a water-soluble binder for Li-O battery

Journal Article

Ion conduction path in composite solid electrolytes for lithium metal batteries: from polymer rich to

Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO

Journal Article

Preparation of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its

Journal Article

A modified pulse charging method for lithium-ion batteries by considering stress evolution, charging

Yanfei ZHAO, Bo LU, Yicheng SONG, Junqian ZHANG

Journal Article

coated LiNi0.5Mn1.5O4 as the high performance cathode materials for lithium-ionbatteries

Shifeng YANG, Wenfeng REN, Jian CHEN

Journal Article

Development of Lithium-Ion Batteries Wins Nobel Prize

Sean O’Neill

Journal Article